Catalytic oxidation of alkanes by iron bispidine complexes and dioxygen: oxygen activation versus autoxidation.
نویسندگان
چکیده
Organic substrates (specifically cis-1,2-dimethylcyclohexane, DMCH) are oxidized by O2 in the presence of iron(II)-bispidine complexes. It is shown that this oxidation reaction is not based on O2 activation by the nonheme iron catalysts as in Nature but due to a radical-based initiation, followed by a radical- and ferryl-based catalytic reaction.
منابع مشابه
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عنوان ژورنال:
- Chemical communications
دوره 50 4 شماره
صفحات -
تاریخ انتشار 2014